{"id":29767,"date":"2021-03-29T08:31:01","date_gmt":"2021-03-29T08:31:01","guid":{"rendered":"http:\/\/sitepourvtc.com\/?page_id=29767"},"modified":"2023-09-07T08:02:01","modified_gmt":"2023-09-07T08:02:01","slug":"titanium-alloys","status":"publish","type":"page","link":"https:\/\/sitepourvtc.com\/nuclear-engineering\/metals-what-are-metals\/alloys-composition-properties-of-metal-alloys\/titanium-alloys\/","title":{"rendered":"Titanium Alloys"},"content":{"rendered":"
<\/a>Titanium<\/strong> is a lustrous transition metal with a silver color, low density<\/strong>, and high strength<\/strong>. Titanium is resistant to corrosion<\/strong> in seawater, aqua regia, and chlorine. In power plants, titanium can be used in surface condensers<\/a>. The Kroll and Hunter processes<\/strong> extract the metal from its principal mineral ores. Kroll\u2019s process involved a reduction of titanium tetrachloride (TiCl4), first with sodium and calcium and later with magnesium, under an inert gas atmosphere. Pure titanium is stronger than common, low-carbon steels but 45% lighter. It is also twice as strong as weak aluminium alloys<\/a> but only 60% heavier. The two most useful properties of the metal are corrosion resistance<\/strong> and strength-to-density ratio<\/strong>, the highest of any metallic element. The corrosion resistance of titanium alloys at normal temperatures is unusually high. Titanium\u2019s corrosion resistance is based on forming a stable, protective oxide layer. Although \u201ccommercially pure\u201d titanium has acceptable mechanical properties and has been used for orthopedic and dental implants, titanium is alloyed with small amounts of aluminium and vanadium, typically 6% and 4%, respectively, for most applications by weight. This mixture has a solid solubility that varies dramatically with temperature, allowing it to undergo precipitation strengthening<\/strong>.<\/p>\n Titanium alloys<\/strong> are metals that contain a mixture of titanium and other chemical elements. Such alloys have high tensile strength and toughness (even at extreme temperatures). They are light in weight, have extraordinary corrosion resistance,<\/strong> and can withstand extreme temperatures.<\/p>\n Titanium exists in two crystallographic forms. At room temperature, unalloyed (commercially pure) titanium has a hexagonal close-packed (hcp)<\/strong><\/a> crystal structure referred to as the alpha (\u03b1) phase<\/strong>. When the temperature of pure titanium reaches 885 \u00b0C (called the \u03b2 transit temperature of titanium), the crystal structure changes to a bcc structure<\/strong><\/a> known as the beta (\u03b2) phase<\/strong>. Alloying elements either raise or lower the temperature for the \u03b1-to- \u03b2 transformation, so alloying elements in titanium are classified as either \u03b1 stabilizers or \u03b2 stabilizers. For example, vanadium, niobium, and molybdenum decrease the \u03b1-to-\u03b2 transformation temperature and promote the formation of the \u03b2 phase.<\/p>\n Pure titanium and its alloys are commonly defined by their grades defined by ASTM Internation standards. In general, there are almost 40 grades of titanium and its alloys. Following is an overview of the most frequently encountered titanium alloys<\/strong> and pure grades<\/strong>, their properties, benefits, and industrial applications.<\/p>\n The two most useful properties of the metal are corrosion resistance<\/strong> and strength-to-density ratio<\/strong>, the highest of any metallic element. The corrosion resistance of titanium alloys at normal temperatures is unusually high. These properties determine the application of titanium and its alloys. The earliest production application of titanium was in 1952 for the nacelles and firewalls of the Douglas DC-7 airliner. High specific strength, good fatigue resistance and creep life, and good fracture toughness are characteristics that make titanium a preferred metal for aerospace applications<\/strong>. Aerospace applications, including use in both structural (airframe) components and jet engines, still account for the largest share of titanium alloy used. On the supersonic aircraft SR-71<\/strong>, titanium was used for 85% of the structure. Due to its very high inertness, titanium has many biomedical applications based on its inertness in the human body, that is, resistance to corrosion by body fluids.<\/p>\n In nuclear power plants, the main steam condenser<\/strong> (MC) system is designed to condense<\/strong> and deaerate<\/strong> the exhaust steam from the main turbine and provide a heat sink for the turbine bypass system. The exhaust steam from the LP turbines is condensed by passing over tubes containing water from the cooling system. These tubes are usually made of stainless steel, copper alloys, or titanium, depending on several selection criteria (such as thermal conductivity or corrosion resistance). Titanium condenser tubes<\/strong> are usually the best technical choice. However, titanium is a very expensive material, and titanium condenser tubes are associated with very high initial costs. Titanium, in particular, can bring major improvements, such as higher water velocities promoting better heat coefficients and excellent resistance to abrasion, erosion, and corrosion, thereby improving resistance to fouling. Tubes are mostly welded tubes from ASTM SB 338 grade 1 made on a continuous manufacturing line. This commercially pure titanium is the softest titanium and has the highest ductility. It has a good cold forming characteristics and provides excellent corrosion resistance. It also has excellent welding properties and high impact toughness. All manufacturing operations (welding, annealing, non-destructive testing) are fully automated to produce high-quality tubes in large quantities.<\/p>\n Material properties<\/strong> are intensive properties<\/strong>, which means they are independent of the amount<\/strong> of mass and may vary from place to place within the system at any moment. Materials science involves studying materials\u2019 structure and relating them to their properties (mechanical, electrical, etc.). Once materials scientist knows about this structure-property correlation, they can then go on to study the relative performance of a material in a given application. The major determinants of a material\u2019s structure and, thus, its properties are its constituent chemical elements and how it has been processed into its final form.<\/p>\n The density of typical titanium alloy<\/strong> is 4.43 g\/cm3<\/sup> (Ti-6Al-4V<\/strong>).<\/p>\n Density<\/strong>\u00a0is defined as the\u00a0mass per unit volume<\/strong>. It is an intensive property<\/strong>, which is mathematically defined as mass divided by volume:<\/p>\n \u03c1 = m\/V<\/strong><\/p>\n In words, the density (\u03c1) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter<\/strong>\u00a0(kg\/m3<\/sup><\/strong>). The Standard English unit is pounds mass per cubic foot<\/strong>\u00a0(lbm\/ft3<\/sup><\/strong>).<\/p>\n Since the density (\u03c1) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious that the density of a substance strongly depends on its atomic mass and also on the atomic number density<\/strong>\u00a0(N; atoms\/cm3<\/sup>),<\/p>\n Materials are frequently chosen for various applications because they have desirable combinations of mechanical characteristics. For structural applications, material properties are crucial, and engineers must consider them.<\/p>\n In the mechanics of materials, the strength of a material<\/strong><\/a> is its ability to withstand an applied load without failure or plastic deformation. The strength\u00a0of materials<\/strong> considers the relationship between the external loads<\/strong> applied to a material and the resulting deformation<\/strong> or change in material dimensions. The strength\u00a0of a material<\/strong> is its ability to withstand this applied load without failure or plastic deformation.<\/p>\n The ultimate tensile strength of commercially pure titanium \u2013 Grade 2 <\/strong>is about 340 MPa.<\/p>\n The ultimate tensile strength of Ti-6Al-4V \u2013 Grade 5 titanium alloy<\/strong> is about 1170 MPa.<\/p>\n <\/a>The ultimate tensile strength<\/strong><\/a> is the maximum on the engineering stress-strain curve<\/a>. This corresponds to the maximum stress<\/strong> sustained by a structure in tension. Ultimate tensile strength is often shortened to \u201ctensile strength\u201d or \u201cthe ultimate.\u201d If this stress is applied and maintained, a fracture will result. Often, this value is significantly more than the yield stress (as much as 50 to 60 percent more than the yield for some types of metals). When a ductile material reaches its ultimate strength, it experiences necking where the cross-sectional area reduces locally. The stress-strain curve contains no higher stress than the ultimate strength. Even though deformations can continue to increase, the stress usually decreases after achieving the ultimate strength. It is an intensive property; therefore, its value does not depend on the size of the test specimen. However, it depends on other factors, such as the specimen preparation, the presence or otherwise of surface defects, and the temperature<\/strong> of the test environment and material. Ultimate tensile strengths<\/strong> vary from 50 MPa for aluminum to as high as 3000 MPa for very high-strength steels.<\/p>\n The yield strength of commercially pure titanium \u2013 Grade 2 <\/strong>is about 300 MPa.<\/p>\n The yield strength of Ti-6Al-4V \u2013 Grade 5 titanium alloy<\/strong> is about 1100 MPa.<\/p>\n The yield point<\/strong><\/a> is the point on a stress-strain curve<\/a> that indicates the limit of elastic behavior and the beginning plastic behavior. Yield strength<\/strong> or yield stress is the material property defined as the stress at which a material begins to deform plastically. In contrast, the yield point is where nonlinear (elastic + plastic) deformation begins. Before the yield point, the material will deform elastically and return to its original shape when the applied stress is removed. Once the yield point is passed, some fraction of the deformation will be permanent and non-reversible. Some steels and other materials exhibit a behavior termed a yield point phenomenon. Yield strengths vary from 35 MPa for low-strength aluminum to greater than 1400 MPa for high-strength steel.<\/p>\n Young\u2019s modulus of elasticity of commercially pure titanium \u2013 Grade 2 <\/strong>is about 105 GPa.<\/p>\n Young\u2019s modulus of elasticity of Ti-6Al-4V \u2013 Grade 5 titanium alloy<\/strong> is about 114 GPa.<\/p>\n Young\u2019s modulus of elasticity<\/a> is the elastic modulus for tensile and compressive stress in the linear elasticity regime of a uniaxial deformation and is usually assessed by tensile tests. Up to limiting stress, a body will be able to recover its dimensions on the removal of the load. The applied stresses cause the atoms in a crystal to move from their equilibrium position, and all the atoms<\/a> are displaced the same amount and maintain their relative geometry. When the stresses are removed, all the atoms return to their original positions, and no permanent deformation occurs. According to Hooke\u2019s law<\/a>, <\/strong>the stress is proportional to the strain (in the elastic region), and the slope is Young\u2019s modulus<\/strong>. Young\u2019s modulus is equal to the longitudinal stress divided by the strain.<\/p>\n <\/a><\/p>\n Rockwell hardness of commercially pure titanium \u2013 Grade 2 <\/strong>is approximately 80 HRB.<\/p>\n Rockwell hardness of Ti-6Al-4V \u2013 Grade 5 titanium alloy<\/strong> is approximately 41 HRC.<\/p>\n <\/a><\/p>\n Rockwell hardness test<\/strong> is one of the most common indentation hardness tests, that has been developed for hardness testing. In contrast to the Brinell test, the Rockwell tester measures the depth of penetration of an indenter under a large load (major load) compared to the penetration made by a preload (minor load). The minor load establishes the zero position, and the major load is applied and removed while maintaining the minor load. The difference between the penetration depth before and after applying the major load is used to calculate the Rockwell hardness number<\/strong>. That is, the penetration depth and hardness are inversely proportional. The chief advantage of Rockwell hardness is its ability to display hardness values directly<\/strong>. The result is a dimensionless number noted as HRA, HRB, HRC<\/strong>, etc., where the last letter is the respective Rockwell scale.<\/p>\n The Rockwell C test is performed with a Brale penetrator (120\u00b0diamond cone<\/strong>) and a major load of 150kg.<\/p>\n Thermal properties<\/strong>\u00a0of materials refer to the response of materials to changes in their\u00a0temperature<\/a> and the application of heat<\/a>. As a solid absorbs energy<\/a> in the form of heat, its temperature rises, and its dimensions increase. But different materials react<\/strong> to the application of heat differently<\/strong>.<\/p>\n Heat capacity<\/a>, thermal expansion<\/a>, and thermal conductivity<\/a> are often critical in solids\u2019 practical use.<\/p>\n The melting point of commercially pure titanium \u2013 Grade 2 <\/strong>is around 1660\u00b0C.<\/p>\n The melting point of Ti-6Al-4V \u2013 Grade 5 titanium alloy<\/strong> is around 1660\u00b0C.<\/p>\n In general,\u00a0melting<\/strong>\u00a0is a\u00a0phase change<\/strong> of a substance from the solid to the liquid phase. The\u00a0melting point<\/strong><\/a> of a substance is the temperature at which this phase change occurs. The\u00a0melting point\u00a0<\/strong>also defines a condition where the solid and liquid can exist in equilibrium.<\/p>\n The thermal conductivity of commercially pure titanium \u2013 Grade 2 <\/strong>is 16 W\/(m. K).<\/p>\n The thermal conductivity of Ti-6Al-4V \u2013 Grade 5 titanium alloy<\/strong> is 6.7 W\/(m. K).<\/p>\n The heat transfer characteristics of solid material are measured by a property called the thermal conductivity<\/strong><\/a>, k (or \u03bb), measured in\u00a0W\/m.K<\/strong>. It measures a substance\u2019s ability to transfer heat through a material by conduction<\/a>. Note that Fourier\u2019s law<\/strong><\/a> applies to all matter, regardless of its state (solid, liquid, or gas). Therefore, it is also defined as liquids and gases.<\/p>\nTypes of Titanium Alloys<\/h2>\n
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Titanium Grades<\/h2>\n
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Application of Titanium Alloys \u2013 Uses<\/h2>\n
Commercially Pure Titanium \u2013 Grade 1 in Steam Condensers<\/h3>\n
Properties of Titanium Alloys<\/h2>\n
The density of Titanium Alloys<\/h3>\n
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Mechanical Properties of Titanium Alloys<\/h3>\n
Strength of Titanium Alloys<\/h3>\n
Ultimate Tensile Strength<\/h3>\n
Yield Strength<\/h3>\n
Young\u2019s Modulus of Elasticity<\/h3>\n
The hardness of Titanium Alloys<\/h2>\n
Thermal Properties of Titanium Alloys<\/h2>\n
Melting Point of Titanium Alloys<\/h3>\n
Thermal Conductivity of Titanium Alloys<\/h3>\n